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dc.contributor.author Enami, Shinichi en
dc.contributor.author Yamanaka, Takashi en
dc.contributor.author Hashimoto, Satoshi en
dc.contributor.author Kawasaki, Masahiro en
dc.contributor.author Tachikawa, Hiroto en
dc.contributor.author Enami, Shinichi en
dc.contributor.author Yamanaka, Takashi en
dc.contributor.author Hashimoto, Satoshi en
dc.contributor.author Kawasaki, Masahiro en
dc.contributor.author Tachikawa, Hiroto en
dc.date.accessioned 2007-06-11T19:25:08Z
dc.date.accessioned 2007-06-11T19:25:08Z
dc.date.available 2007-06-11T19:25:08Z
dc.date.available 2007-06-11T19:25:08Z
dc.date.issued 2006-10-07
dc.date.issued 2006-10-07
dc.identifier.citation Enami, S., Yamanaka, T., Hashimoto, S., Kawasaki, M., Aloisio, S. and Tachikawa, H., "Direct observation and reactions of Cl3 radical." Journal of Chemical Physics, Volume 125, Issue 13, pp. 133116-133116-6 (2006). en
dc.identifier.citation Enami, S., Yamanaka, T., Hashimoto, S., Kawasaki, M., Aloisio, S. and Tachikawa, H., "Direct observation and reactions of Cl3 radical." Journal of Chemical Physics, Volume 125, Issue 13, pp. 133116-133116-6 (2006). en
dc.identifier.issn 0021-9606
dc.identifier.issn 0021-9606
dc.identifier.uri http://hdl.handle.net/10139/412
dc.identifier.uri http://hdl.handle.net/10139/412
dc.description.abstract The broad absorption of Cl3 radical was observed between 1150 and 1350 nm using cavity ring-down spectroscopy at 213–265 K and 50–200 Torr with He, N2, Ar, or SF6 diluents. The absorption intensity of Cl3 increased at lower temperature and higher pressure. SF6 was the most efficient diluent gas. The temperature dependent equilibrium constants for Cl3 formation from Cl+Cl2 were theoretically calculated at the MP4SDQ/6-311+G(d) level. Observed decay time profiles of Cl3 and the pressure dependence of Cl3 formation are explained by the equilibrium reaction and a decay reaction of Cl+ Cl3. en
dc.description.abstract The broad absorption of Cl3 radical was observed between 1150 and 1350 nm using cavity ring-down spectroscopy at 213–265 K and 50–200 Torr with He, N2, Ar, or SF6 diluents. The absorption intensity of Cl3 increased at lower temperature and higher pressure. SF6 was the most efficient diluent gas. The temperature dependent equilibrium constants for Cl3 formation from Cl+Cl2 were theoretically calculated at the MP4SDQ/6-311+G(d) level. Observed decay time profiles of Cl3 and the pressure dependence of Cl3 formation are explained by the equilibrium reaction and a decay reaction of Cl+ Cl3. en
dc.language.iso en en
dc.language.iso en en
dc.publisher American Institute of Physics en
dc.publisher American Institute of Physics en
dc.relation.ispartofseries Vol. 125 en
dc.relation.ispartofseries Issue 13 en
dc.relation.ispartofseries Vol. 125 en
dc.relation.ispartofseries Issue 13 en
dc.subject chlorine en
dc.subject free radical reactions en
dc.subject spectrochemical analysis en
dc.subject spectral line intensity en
dc.subject chemical equilibrium en
dc.subject perturbation theory en
dc.subject reaction kinetics theory en
dc.subject chlorine en
dc.subject free radical reactions en
dc.subject spectrochemical analysis en
dc.subject spectral line intensity en
dc.subject chemical equilibrium en
dc.subject perturbation theory en
dc.subject reaction kinetics theory en
dc.title Direct observation and reactions of Cl3 radical en
dc.title Direct observation and reactions of Cl3 radical en
dc.type Postprint en
dc.type Postprint en
dc.contributor.csuciauthor Aloisio, Simone en
dc.contributor.csuciauthor Aloisio, Simone en


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