dc.contributor.author |
Enami, Shinichi |
en |
dc.contributor.author |
Yamanaka, Takashi |
en |
dc.contributor.author |
Hashimoto, Satoshi |
en |
dc.contributor.author |
Kawasaki, Masahiro |
en |
dc.contributor.author |
Tachikawa, Hiroto |
en |
dc.contributor.author |
Enami, Shinichi |
en |
dc.contributor.author |
Yamanaka, Takashi |
en |
dc.contributor.author |
Hashimoto, Satoshi |
en |
dc.contributor.author |
Kawasaki, Masahiro |
en |
dc.contributor.author |
Tachikawa, Hiroto |
en |
dc.date.accessioned |
2007-06-11T19:25:08Z |
en |
dc.date.accessioned |
2007-06-11T19:25:08Z |
en |
dc.date.available |
2007-06-11T19:25:08Z |
en |
dc.date.available |
2007-06-11T19:25:08Z |
en |
dc.date.issued |
2006-10-07 |
en |
dc.date.issued |
2006-10-07 |
en |
dc.identifier.citation |
Enami, S., Yamanaka, T., Hashimoto, S., Kawasaki, M., Aloisio, S. and Tachikawa, H., "Direct observation and reactions of Cl3 radical." Journal of Chemical Physics, Volume 125, Issue 13, pp. 133116-133116-6 (2006). |
en |
dc.identifier.citation |
Enami, S., Yamanaka, T., Hashimoto, S., Kawasaki, M., Aloisio, S. and Tachikawa, H., "Direct observation and reactions of Cl3 radical." Journal of Chemical Physics, Volume 125, Issue 13, pp. 133116-133116-6 (2006). |
en |
dc.identifier.issn |
0021-9606 |
en |
dc.identifier.issn |
0021-9606 |
en |
dc.identifier.uri |
http://hdl.handle.net/10139/412 |
en |
dc.identifier.uri |
http://hdl.handle.net/10139/412 |
en |
dc.description.abstract |
The broad absorption of Cl3 radical was observed between 1150 and 1350 nm using cavity ring-down spectroscopy at 213–265 K and 50–200 Torr with He, N2, Ar, or SF6 diluents. The absorption intensity of Cl3 increased at lower temperature and higher pressure. SF6 was the most efficient diluent gas. The temperature dependent equilibrium constants for Cl3 formation from Cl+Cl2 were theoretically calculated at the MP4SDQ/6-311+G(d) level. Observed decay time profiles of Cl3 and the pressure dependence of Cl3 formation are explained by the equilibrium reaction and a decay reaction of Cl+ Cl3. |
en |
dc.description.abstract |
The broad absorption of Cl3 radical was observed between 1150 and 1350 nm using cavity ring-down spectroscopy at 213–265 K and 50–200 Torr with He, N2, Ar, or SF6 diluents. The absorption intensity of Cl3 increased at lower temperature and higher pressure. SF6 was the most efficient diluent gas. The temperature dependent equilibrium constants for Cl3 formation from Cl+Cl2 were theoretically calculated at the MP4SDQ/6-311+G(d) level. Observed decay time profiles of Cl3 and the pressure dependence of Cl3 formation are explained by the equilibrium reaction and a decay reaction of Cl+ Cl3. |
en |
dc.language.iso |
en |
en |
dc.language.iso |
en |
en |
dc.publisher |
American Institute of Physics |
en |
dc.publisher |
American Institute of Physics |
en |
dc.relation.ispartofseries |
Vol. 125 |
en |
dc.relation.ispartofseries |
Issue 13 |
en |
dc.relation.ispartofseries |
Vol. 125 |
en |
dc.relation.ispartofseries |
Issue 13 |
en |
dc.subject |
chlorine |
en |
dc.subject |
free radical reactions |
en |
dc.subject |
spectrochemical analysis |
en |
dc.subject |
spectral line intensity |
en |
dc.subject |
chemical equilibrium |
en |
dc.subject |
perturbation theory |
en |
dc.subject |
reaction kinetics theory |
en |
dc.subject |
chlorine |
en |
dc.subject |
free radical reactions |
en |
dc.subject |
spectrochemical analysis |
en |
dc.subject |
spectral line intensity |
en |
dc.subject |
chemical equilibrium |
en |
dc.subject |
perturbation theory |
en |
dc.subject |
reaction kinetics theory |
en |
dc.title |
Direct observation and reactions of Cl3 radical |
en |
dc.title |
Direct observation and reactions of Cl3 radical |
en |
dc.type |
Postprint |
en |
dc.type |
Postprint |
en |
dc.contributor.csuciauthor |
Aloisio, Simone |
en |
dc.contributor.csuciauthor |
Aloisio, Simone |
en |